Cooking opens the starch
Raw rice starch is packed tight. Heat and water loosen it above about 60C. The grain swells and turns soft. This open starch soaks up liquid fast.
Cooling closes it again
As rice cools, the starch slowly packs tight again. This is called retrogradation. It moves fastest near fridge cold, around 4C. The grain gets firm, dry, and hard to flavor.
When cold rice wins
Fried rice is the opposite case. Firm, cold grains stay apart in a hot pan. They take oil on the outside only.
I set out the vinegar before the rice finishes. Then the rice never waits.